fu'a

nylon maualuga vevela samasama auala faaleleia ma faaleleia fuafuaga

Aliphatic polyamides o fausaga eseese ua gaosia faapisinisi, lea o PA6, PA66, PA46, PA11 ma PA12 e sili ona taua.O le faʻaleagaina o le oxidative i le PA e faʻalagolago i le maualuga o le tioata ma le mamafa o le vaega amorphous.E tusa ai ma le auala masani, o polyamides aliphatic e faʻamautu i ni nai masima apamemea (e oʻo atu i le 50 ppm) faʻatasi ma ions halogen (e pei o iodine ma bromide ions).O le lelei o lenei faiga faʻamautu e ofo ona o ion apamemea ua manatu o se fesoasoani matua i polyolefins.O lo'o su'esu'eina pea le faiga e fa'amautu ai le a'afiaga ole kopa/halogen.

Aromatic amines o faʻamautu masani e faʻateleina le LTTS, ae a faʻaaogaina i le PA, e mafai ona mafua ai le faʻaleagaina o polymers.Phenol antioxidants e mafai ona faʻaleleia le lanu muamua pe a uma le polycondensation e faʻamautu ai le polyamide aliphatic.E masani lava, o lenei antioxidant e faʻaopoopoina aʻo leʻi faʻamutaina le polycondensation reaction.

O le laulau o loʻo i lalo e faʻatusatusa ai meatotino o faʻamautu eseese o loʻo faʻaaogaina mo polyamide aliphatic.

faiga AO Fa'amanuiaga Vaivai
Masima apamemea/iodide E aoga tele i fa'amaumau maualalo

A oʻo i luga ole 150 °C le vevela matua, e saofagā tele i le LTTS o le polymer.

Le lelei le ta'ape i polymers

E faigofie ona fa'amama pe a fa'afeso'ota'i ma vai po'o vai/solvents

E ono tupu ai le liu lanu

Amines manogi E fesoasoani tele i le LTTS o polymers Ia i ai i tulaga maualuga

felanulanua'i

Phenols E fesoasoani tele i le LTTS o polymers

Lelei le faatinoga o lanu

E mafai ona faʻaopoopo i le taimi o le faʻatonuga

E leai ni itu e tutupu i isi polymers a'o fa'afefiloi

I le maualuga o le vevela o le matua (fa'ata'ita'iga i luga atu o le 150°C), o faiga fa'amautu kopa/iodide e fa'aalia ai fa'ai'uga sili.Ae ui i lea, i le maualalo o le vevela o le matua, phenolic antioxidants naʻo pe faʻatasi ma phosphites e mafai ona sili atu le aoga.O le isi fa'amanuiaga o le fa'aogaina o le phenolic antioxidants o lo'o latou fa'atumauina le lanu muamua o polypolymers se'ia o'o ina fa'atupuina le vevela e sili atu le lelei nai lo mea fa'amautu masima kopa.

O le fa'alia o le polymer pe a uma le vevela vevela e le fa'aitiitia fa'atasi ma ona mea fa'ainisinia.E mafai ona tupu le fa'alilolilo e o'o lava i se vaitaimi pu'upu'u o le matua, peita'i o le malosi fa'a'umi'umi ma le fa'aumiumi o le polymer o le a le a'afia seia o'o i se taimi mulimuli ane.

O se tino tele o tusitusiga o loʻo faʻamatalaina ai le tele o faʻaoga o polyamides faʻamalosia tioata-fiber i totonu o fale taʻavale, e pei o lau afi afi, pulou faʻamalo ma grilles, taofi ma faʻapipiʻi eletise eletise, lima valve, paʻu, faʻafesoʻotaʻi taofi ea ma pulou.Phenolic antioxidants, pe naʻo pe faʻatasi ma le phosphite, o mea sili ona lelei mo le GFR PA66.

O le fua faʻavae o le phenol + phosphite tuʻufaʻatasiga o le 1098 + 168, lea e mafai ona faʻaaogaina i le maualalo o le vevela ole faʻaleleia, ma faʻaleleia le lanu faʻafefe.Ae ui i lea, mo faiga polyamide e pei o le fiber tioata faʻamalosia, o le gaosiga o le vevela e maualuga atu (toetoe lava 300 °C), 168 maualuga le vevela male faʻaleagaina, i le taimi nei, e tele lava ina matou faʻaaogaina le 1098 + S9228 o se tuʻufaʻatasiga sili atu le vevela, lea e faʻapea foi. o le fua fa'aaoga e sili ona fa'aaogaina i le nylon vevela maualuga.

I le maeʻa ai o faʻaiʻuga o suʻega, e maua ai le 1098 + S9228 o loʻo i ai pea le avanoa mo le faʻaleleia atili o le lanu o le nylon vevela maualuga, ma faʻalauiloa e le Sarex Chemical oloa faʻaleleia SARAFOS 2628P5 (faʻapipiʻi faʻavae phosphorus) ma SARANOX PA2624 (faʻalavelave phenol ma phosphite. tu'ufa'atasiga) e sili atu le fa'atinoga i le samasama o le nylon maualuga-vevela, ma o fa'amaumauga talafeagai o su'ega e fa'apea:

PA66, 270°C tele extrusion ma suʻega tao vevela
metotia fa'aleleia ma fa'aleleia fuafuaga (1)

■0.1%1098+0.2%9228 8.32 15.5 21.11 33.71
■0.1%109810.2%2628P5 3.85 10.88 17.02 21.16
■3%PA2624 -3.25 1.87 4.94 12.21

O faʻamaumauga o loʻo i luga na fuafuaina e le Sarex Chemical Laboratory

Pe a faatusatusa i le aofaiga tutusa o le faaopoopoga o le SARAFOS 2628P5 ma le S9228, o le lanu o le tele o extrusion ma 120 °C vevela teuina mo le 12h e lelei le faatinoga, ma le hydrolysis tetee o le oloa lava ia e sili atu nai lo le S9228, lea e lelei le faaaogaina. fa'amoemoega ile suiga ole PA.
A iai ni manaʻoga maualuga atu mo le lanu muamua, e fautuaina e faʻaopopo le SARANOX PA2624, faʻaopoopo i le paʻu paʻu, e mafai foi ona matou tuʻuina atu i tagata faʻatau le PA antioxidant masterbatches ma le ave-free antioxidant particles, lea e faigofie ona faʻaopoopo ma faʻasalalau, ma fesoasoani. le faleaoga gaosiga ina ia leai se pefu.

PA66, tele extrusion i le 270 °C 0.1%1098+0.2%9228 0.1%1098+0.2%2628P5 0.3%PA2624
1 extrusion  metotia fa'aleleia ma fa'aleleia le fuafuaga (2)  metotia fa'alelei ma fa'aleleia fuafuaga (3)  metotia fa'aleleia ma le fa'aleleia o fuafuaga (4)
3 extrusions  metotia fa'aleleia ma fa'aleleia fuafuaga (5)  metotia fa'alelei ma fa'aleleia fuafuaga (6)  metotia fa'alelei ma fa'aleleia fuafuaga (7)
5 extrusions  metotia fa'alelei ma fa'aleleia fuafuaga (8)  metotia fa'alelei ma fa'aleleia fuafuaga (9)  metotia fa'aleleia ma fa'aleleia fuafuaga (10)
Tao i le 120°C, 12h

 

 metotia fa'alelei ma fa'aleleia fuafuaga (11)  metotia fa'alelei ma fa'aleleia fuafuaga (12)  metotia fa'alelei ma fa'aleleia fuafuaga (13)

O faʻamaumauga o loʻo i luga na fuafuaina e le Sarex Chemical Laboratory


Taimi meli: Nov-14-2022